· As pH decreased to <10, most of the Cr(VI) bearing minerals become unstable and their dissolution contributes to the increase in Cr(VI) concentration in the leachate solution. At low pH (<), Cr(III) solid phases and the oxides responsible for Cr(VI) adsorption dissolve and release Cr(III) and Cr(VI) into solution.
chromite, the Survey instituted a program aimed at increasing the speed and accuracy of chromite analysis. Various methods and schemes of analysis were critically studied. The most satisfactory were rigorously tested on previously analyzed materials. A description of the current status of the methods is presented here. 31
Naturally occurring Cr(VI) in groundwater has been identified in the fol, centrations at a high pH are most likely Cr(VI) 3123 Chromite Ore Bodies. 【Service Online】 Physical Chemistry of Roasting and Leaching Reactions. The natural resource of chromium is the chromite ore,, oxide production from chromite concentrate by alkali fusion ...
· · As pH decreased to <10, most of the Cr(VI) bearing minerals become unstable and their dissolution contributes to the increase in Cr(VI) concentration in the leachate solution. At low pH (<), Cr(III) solid phases and the oxides responsible for Cr(VI) adsorption dissolve and release Cr(III) and Cr(VI) into solution.
· The present study reports the isolation of Cr(VI) resistant bacterial strains from an Indian chromite mine soil and their potential use in reduction of hexavalent chromium. RESULTS: Among the isolates, a bacterial strain (CSB4) was identified as Bacillus sp. based on standard biochemical tests and partial 16SrRNA gene sequencing, which was tolerant to as high as 2000 mg L −1 Cr(VI ...
To avoid the transformation from Cr(III) into Cr(VI) in the chromite processing, sulfuric acid leaching has been proposed and extensively studied [26–29]. In this process, Cr(III) is extracted from the chromite in a heated sulfuric acid solution with the help of recovered dichromic acid, with Cr(III) salts as .
In the experiments, chromite ore concentrate from the Pınarba¸sı region of Kayseri province in Turkey,sulfuricacid(9597wt%H 2SO 4)andperchloric acid (60 wt % HClO 4)wereusedasstartingmaterials. XRFanalysisoftheconcentratewas performed at the MTA (Maden TetkikArama Enstit¨us¨u) andshowedthatthe concentrate consisted %Cr 2O 3, ...
Almost complete reduction of Cr(VI) in the chromite concentrate was achieved in ~ 12 min of incubation under the optimized conditions of pH ~, 35 °C temperature and 60% pulp density with the ...
Hexavalent chromium (chromium(VI), Cr(VI), chromium 6) is chromium in any chemical compound that contains the element in the +6 oxidation state (thus hexavalent).Virtually all chromium ore is processed via hexavalent chromium, specifically the salt sodium chromium is key to all materials made from chromium.
· Effect of Initial Cr(VI) Concentration. The effect of different initial Cr(VI) concentrations (50–800 μM) were tested on Cr(VI) reducing ability of Arthrobacter sp. SUK 1201. The results presented in Table 1 showed that cells of SUK 1201 completely reduced 50 and 100 μM Cr(VI) 24 h and in 48 h respectively. The other concentrations of Cr(VI) were also significantly reduced within 48 h ...
Cr Vi In Chromite Concentrate. Chromite ore can be mined to produce chromite can also be crushed and concentrate, when combined with a reductant such as coal or coke and a high temperature furnace can produce is a type of ferroalloy that is an alloy in between chromium and iron.
For the chromite ore samples, the total Cr content in the solid ranges between 203 and 236 g/kg. For the chromite ore 1, Cr(VI) extracted with water is equivalent to total Cr extracted with KH 2 PO 4, with an average value of mg/kg, while the Cr(VI) extracted with KH 2 PO 4 .
· 1. Introduction. Chromite ore processing residue (COPR) is an industrial waste generated during the extraction of Cr(VI) from chromite ore using the hightemperature limebased roasting process [,, ].When COPR undergoes weathering reactions during the deposition process, it would release highly toxic and mobile Cr(VI) due to the destabilization and dissolution of the mineral phases in COPR [4,5].
Almost complete reduction of Cr(VI) in the chromite concentrate was achieved in ~ 12 min of incubation under the optimized conditions of pH ~, 35 °C temperature and 60% pulp density with the ...
Cr(VI) Chromite Ferrochrome Ring of Fire Canada abstract During stainless steel production, new chromium units are obtained from ferrochrome, a relatively crude alloy produced from chromite ore. Large chromite reserves have recently been discovered in the socalled Ring of Fire, Canada.
Cr(VI) has a single, intense preedge XANES feature that allows detection at low concentration 5985 6000 6015 6030 6045 6060 6075 Energy (eV) Sodium chromate (NaCrO 4) Mahlerbe Chromite (Cr 3O 4) Preedge Cr(VI) Cr(III) Detection limits of Cr(VI) by XANES 02% Cr(VI) in Cr(III)dominated matrix Absolute concentration: 100 mg/kg Cr(VI) et al.
· The average grade of the metallurgical chromite ore was pct Cr2O3, with 52 pct of the ore having a chromiumtoiron ratio of 3:1 or over, pct having a ratio between 2:1 and 3:1, and pct having a ratio less than 2:1. Chemicalgrade chromite ore generally ranged from 40 to 46 pct Cr2O3 with a chromiumtoiron ratio of :1 to 2:1.
Cr(VI) generated due to natural oxidation of chromite mineral present in chromite mine overburden (COB) dumps of Sukinda, India, has been characterized by different physicochemical methods. The Cr(VI) was found to be associated with goethite matrix at a contamination level of 500 mg Cr(VI.
e concentration of hexavalent chromium (Cr(VI)), a toxic environmental pollutant and carcinogen, was determined in samples collected from Nacogdoches Wastewater Treatment Plant (NWWTP) using ion chromatography and UVvisible spectrophotometry (IC, UVVis).
regulate the concentration of Cr(VI) in drinking and wastewaters and require that its concentration is measured and reported. The state of California, for example, has established a public health goal (PHG) of µg/L Cr(VI) in drinking water. Dissolved hexavalent chromium can
Cr 2O 3) but also the concentrator achieved a stringent target SiO 2 grade of % in the concentrate. The approach adopted and practical problems encountered during the study are reported in this paper. Keywords chromite ore, characterization, QEMSCAN, gravity concentration.
Cr(VI), with the remainder existing as the trivalent Cr(III) However, when COPR is mixed with other materials, the Cr(VI) concentration in the mixture varies widely. Cr(VI) rarely occurs naturally and is highly mobile in the environment, acutely toxic at moderate doses, and classified as a known respiratory carcinogen in hu
34 Chromium obtaining from armenian chromite concentrates by SHS in the presence of chlorides may be seen the concentrate mainly is composed of chromspinellide and magniochromite. Magnetite occurs in free form. Vibration planetary mill (2474 rpm) of ML30 type was used for grinding (pretreatment) of the chromite concentrate (down to
The concentration of hexavalent chromium (Cr(VI)), a toxic environmental pollutant and carcinogen, was determined in samples collected from Nacogdoches Wastewater Treatment Plant (NWWTP) using ion chromatography and UVvisible spectrophotometry (IC, UVVis). On reaction with 1,5diphenylcarbazide (DPC) Cr +6 forms a 1,5diphenylcarbazideCr(VI) complex, which is then .
increase in Cr(VI) concentration, but is still within the stipulated standards for drinking and bathing water. It should, however, be borne in mind that the water quality of Damsala river with respect to Cr(VI) is governed by the quality of discharge of the treated mine drainage water (Tables – 9 and 10).